The invention relates to vinyl acetate ethylene copolymer emulsion vae emulsion and a synthesis method thereof. Msds, safety data sheet sds and any other materials provided. Before using or handling vinyl acetate monomer vam, read the material safety data sheet msds, safety data sheet sds and any other materials provided by your supplier. Your new online msds binder is a place for you to store the material safety data sheets. Vinyl acetate monomer is chemical building block used for a wide variety of.
Material safety data sheet of vinyl acetate monomer slideshare. Presented at the 2006 ieee 4th world conference on photovoltaic energy conversion wcpec4 held may 712, 2006 in waikoloa, hawaii. Since vinyl alcohol is highly unstable with respect to acetaldehyde, the preparation of vinyl acetate is more complex than the synthesis of other acetate. This product is not dangerous under directive 199945ec and subsequent amendments. Vinyl acetate 108054 hazard summary vinyl acetate is primarily used as a monomer in the production of polyvinyl acetate and polyvinyl alcohol. Material safety data sheetmsds ethyl acetate synonyms. Before using or handling vinyl acetate monomer vam, read the material safety data sheet. Copying andor downloading of this information for the purpose of properly utilizing 3m. The major industrial route involves the reaction of ethylene and acetic acid with oxygen in the presence of a palladium catalyst.
Astm d5594 18a standard test method for determination of. Material safety data sheet according to 19072006ec. The chemical identity of vinyl acetate is shown in table 31. Vinyl acetate monomer free download as powerpoint presentation. Revised october 24, 2006 flexible vinyl msds material safety. It is a clear, colorless liquid with a sweet, fruity smell. These polymers are the base for many industrial and consumer products as well as for other polymers. Msds vam vinyl acetate monomer free download as pdf file. Ethylene vinyl acetate evapolyvinyl chloride graft copolymer taiyo vinyl tg. Acute shortterm inhalation exposure of workers to vinyl. Sep 28, 2011 vinyl acetate is a volatile liquid that polymerizes in light to a colorless, transparent mass and usually contains an inhibitor, such as hydroquinone. Vinyl acetate emulsion polymerization and copolymerization with acrylic monomers provides a collection and logical organization of the published data much of it formerly found fragmented.
Vinyl acetate is the acetate ester of vinyl alcohol. Material safety data sheet poly vinyl acetate, average m. Presented at the 2006 ieee 4th world conference on photovoltaic energy conversion. Vinyl acetate is a particularly interesting substrate, since, as mentioned earlier, it gives 2acetoxypropanal, a precursor in the strecker synthesis of threonine.
Vinyl acetate monomer safety data sheet international. Vinyl acetate monomer vam is a highvolume building block chemical used in the manufacture of polyvinyl acetate or vinyl acetate copolymers. Cn102030858b vinyl acetateethylene copolymer emulsion. A wide variety of msds vinyl acetate options are available to you, such as grade standard. Find msds or sds, a coa, data sheets and more information.
Material safety data sheet ehylene vinyl acetate copolymer section disposal considerations waste disposal the generation of waste should be avoided or minimized wherever possible. Sigmaaldrich offers a number of vinyl acetate products. Dusts and vapours or fumes evolved during thermal processing may cause irritation to the respiratory. Dusts and vapours or fumes evolved during thermal processing may cause irritation to the respiratory system. Inhalation of vapors may result in dizziness or suffocation. The synthesis method comprises the processes of preemulsification, emulsion polymerization reaction, finishing and defoaming. Revised october 24, 2006 flexible vinyl msds material. Vinyl acetate monomer presenation personal protective. Weight percent vinyl acetate varies from 10 to 40 %. When handled properly, vam can be stored, transported and otherwise managed safely.
Ethylene vinyl acetate an overview sciencedirect topics. Acute exposure to vinyl acetate monomer may require decontamination and life support for the victims. Vinyl acetate msds material safety data sheet or sds, coa and coq, dossiers, brochures. Otherinformation hazardousmaterialinformationsystemusa health 1 firehazard 0 reactivity 0 disclaimer the. The basis for the proposed limits is an epidemiologic report by deese and joyner 1969ex. Download vinyl acetate monomer safety data sheet international. All books are in clear copy here, and all files are secure so dont worry about it. Material safety data sheet of vinyl acetate monomer. Acute shortterm inhalation exposure of workers to vinyl acetate has resulted in eye irritation and upper. Material safety data sheet ehylenevinyl acetate copolymer section 1 product and company identification. The invention relates to vinyl acetateethylene copolymer emulsion vae emulsion and a synthesis method thereof. Vinyl acetate is a volatile liquid that polymerizes in light to a colorless, transparent mass and usually contains an inhibitor, such as hydroquinone.
International vinyl acetate company safety data sheet according to regulation ec no. Since vinyl alcohol is highly unstable with respect to acetaldehyde, the preparation of vinyl acetate is more complex than the synthesis of other acetate esters. Please ensure that this msds is given to, and explained to people using this product. Vam can be polymerized in mass, solution, suspension or emulsion. If there is potential for inhalation of dust or vapor, wear a niosh approved respirator. Ethylene vinyl acetate copolymer does not have an acid odor if it is not thermally degraded.
It is very flammable and may be ignited by heat, sparks, or flames. Material safety data sheet msds vinyl acetate monomer s. Xu indicates a substance exempt from reporting under the chemical data reporting rule, 40 cfr 711. Vinyl acetate with an inhibitor level of 35 ppm hydroquinone should not be stored longer than six months at 2127 deg c 7080 deg f, or longer than one year with 1417 ppm hydroquinone. Material safety data sheet polyvinyl acetate, average m. Vinyl acetate is a colorless, flammable liquid that also has a characteristic smell that can quickly become irritating.
This product has been classified in accordance with the hazard. These polymers are the base for many industrial and. Ethylene vinyl acetate eva is a random copolymer of ethylene and varying amounts of vinyl acetate va. Potential problems with ethylenevinyl acetate for photovoltaic packaging poster author. D559418a standard test method for determination of the vinyl acetate content of ethylene vinyl acetate eva copolymers by fourier transform infrared spectroscopy ftir vinyl acetate content ethylene vinyl acetate copolymer. Material safety data sheet ethylene vinyl acetate copolymer 14% vinyl acetate. Material safety data sheet according to 19072006ec, article 31.
Vinyl acetate from ethylene, acetic acid and oxygen. Vinyl acetate occurs as residual monomer in homo and copolymers based on vinyl acetate and in products or formulations based on these polymers. Vinyl acetate monomer polyvinyl chloride materials science. Vinyl acetate monomer vam silver fern chemical inc. Download technical data sheet vinyl acetate monomer vam download sds. Vinyl acetate vapors are uninhibited and may form polymers in vents or flame arrestors of storage tanks, resulting in plugging of vents. Msds of ethylene vinyl acetate emulsion ethylene vinyl acetate emulsion da128h download file pdf. Polyvinyl acetate sds ghs, msds sheet of manufacturers. Page 1 of 7 msds vinyl acetate monomer material safety data sheet msds vinyl acetate monomer 1. Potential problems with ethylene vinyl acetate for photovoltaic packaging poster author. This monomer is used principally in the production of polyvinyl acetate pvac and other. Vaporphase vinyl acetate may also be deg raded in the atmosphere by reaction with ozone with an estimated halflife of 3.
This msds has been prepared according to the hazard criteria of t he controlled products regulations cpr and the msds contains all of the information required by the cpr. It is very flammable and may be ignited by heat, sparks, or. Cn102030858b vinyl acetateethylene copolymer emulsion vae. Vinyl acetate monomer presenation free download as powerpoint presentation. Identification of the substancemixture and of the responsible company 1. A wide variety of msds vinyl acetate options are available to you, such as grade. George wypych, in handbook of odors in plastic materials second edition, 2017. The synthesis method comprises the processes of preemulsification, emulsion. Polyvinyl acetate sds ghs, msds sheet of manufacturers commercial pure, bp and fcc food grade polyvinyl acetate sds ghs, msds sheet of manufacturers anmol chemicals is the pioneer. Vinyl acetate monomer vam is a high volume building block chemical used in the manufacture of polyvinyl acetate or vinyl acetate copolymers. Your new online msds binder is a place for you to store the material safety data sheets you need to deploy.
D559418a standard test method for determination of the vinyl acetate content of ethylenevinyl acetate eva copolymers by fourier transform infrared spectroscopy ftir vinyl acetate content. Information concerning particular hazards for human and environment. Aug 25, 2017 vinyl acetate with an inhibitor level of 35 ppm hydroquinone should not be stored longer than six months at 2127 deg c 7080 deg f, or longer than one year with 1417 ppm hydroquinone. The physical and chemical properties of vinyl acetate are shown in table 32. Signs and symptoms of acute vinyl acetate monomer exposure. Polyvinyl acetate is a precursor of polyvinilyc alcohol and polyvinyl acetate resins pva. Msds vam vinyl acetate monomer acetic acid explosive material. View or download the vinyl acetate msds material safety data sheet or sds for 803184 from merck. Product and company information hoehn plastics inc. Vinyl acetate emulsion polymerization and copolymerization. This monomer is used principally in the production of polyvinyl acetate pvac and other vinyl acetate copolymers.
Vinyl acetate monomer safety data sheet international vinyl acetate company safety data sheet according to regulation ec no. Disclaimer of expressed and implied warranties the information presented in the material safety data sheet is based on data believed to be accurate as of. Read online vinyl acetate monomer safety data sheet international. Vinyl acetate is used to make other industrial chemicals. Vinyl acetate 108054 trace trace impurities and additional material. Guide is intended to be used in conjunction with the manufacturers information. Vinyl acetate monomer vinyl ester acetic acid back to top product overview vinyl acetate monomer vam is an essential chemical building block used in a wide variety of industrial and consumer. Biodegradability of polyvinyl acetate and related polymers article pdf available in advances in polymer science 245. Pdf biodegradability of polyvinyl acetate and related.
With free acrobat readerr software you can view and print adobe pdf files. Material safety data sheet or sds for vinyl acetate 803184 from merck for download or viewing in the browser. Vinyl acetate monomer vam is used for the production of polymer emulsions of various types, which are base resins for waterbased paints, adhesives, paper coatings and textile finishes. Vinyl acetate is an industrial chemical that is produced in large amounts in the united states. Vinyl acetate monomer may irritate the skin, eyes, and respiratory tract. Eu risk assessment vinyl acetate summary, 2008 8 copolymers.
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